主管：中华人民共和国司法部
主办：司法鉴定科学研究院
ISSN 1671-2072  CN 31-1863/N
中国司法鉴定

中国司法鉴定 ›› 2010 ›› Issue (6): 16-26.

• •    下一篇

ATD-GC-MS测定火场样品中痕量汽油燃烧残留

邢若葵, 王松才, 戴维列等   

  1. 广州市刑事科学技术研究所，广东 广州510030
  • 收稿日期:2010-08-10 出版日期:2010-11-15 发布日期:2022-07-07
  • 作者简介:邢若葵（1956-），高级工程师，主要从事微量物证鉴定工作。
  • 基金资助:
    广州市科技攻关项目（2007Z1-E0062）

Analysis of Trace Gasoline Residues from Fire Debris Samples by ATD-GC-MS and Discussion on the Presence of Gasoline

XING Ruo-kui,WANG Song-cai, DAI Wei-lie, etc.   

  1. Guangzhou Institute of Criminal Science Technology,Guangzhou 510030, China
  • Received:2010-08-10 Published:2010-11-15 Online:2022-07-07

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摘要： 目的 为火场样品中痕量汽油残留物的检测建立一种简便、高灵敏度的检验方法和可靠的检验结果评判方法。方法 用 Tenax TA吸附管吸附富集火场样品中的汽油成分，然后用 ATD-GC-MS法自动解吸和检测。通过模拟燃烧实验，探讨了检验结果的评判方法∶根据样品的 m/z (57.85)、m/z (91+105+119)、m/z (117+131)和 m/z (128+142+156) 四个质量色谱图与已知汽油作比较来对检验结果作评判。结果6组模拟燃烧实验中凡有汽油作助燃剂的样品，均检出汽油残留物成分。结论 所建立的方法具有操作简便，检测灵敏度高，杂质干扰少，定性结论准确可靠等特点，可用于实际火场样品中痕量汽油残留物的检测。

关键词: Tenax TA吸附管, 自动热脱附-气相色谱-质谱, 火场样品, 汽油

Abstract: Objective To establish a simple and sensitive method of analyzing trace gasoline from fire debris samples. Methods Gasoline from fire debris was absorbed and enriched by Tenax TA kit and then desorbed and analyzed by ATD-GC-MS. A series of simulation combustion experiments were taken. Interpretation of the results or the presence of gasoline was discussed by comparing four groups extracted ion chromatograms (m/z 57+85. m/z 91+105+119. m/z117+131. m/z 128+142+156)of fire debris samples with that of known gasoline. Results Gasoline residue components were detected in the six sets of combustion experiment samples in which gasoline was used as accelerant. Conclusion The method has the advantage of automatic desorbing and analyzing, simple and quick operation, high sensitivity and lower impurity interference. It can be used in the analysis of residues of gasoline collected at fire scenes.

Key words: Tenax TA Kit, ATD-GC-MS, fire debris sample, gasoline

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